Updated on 2026/05/25

写真a

 
HATTORI, Shingo
 
Affiliation
Faculty of Science and Engineering, Waseda Research Institute for Science and Engineering
Job title
Junior Researcher(Assistant Professor)
Degree
Ph.D. ( The University of Tokyo )

Research Experience

  • 2026.04
    -
    Now

    Waseda University   Lecturer

  • 2024.04
    -
    2026.03

    Waseda University   Lecturer

  • 2019.04
    -
    2026.03

    Yokohama City University   Assistant Professor

  • 2017.04
    -
    2019.03

    The University of Tokyo   Researcher

  • 2018.10
    -
    2018.12

    The University of Leuven   Researcher

Education Background

  • 2014.04
    -
    2017.03

    The University of Tokyo   Doctoral Degree  

  • 2012.04
    -
    2014.03

    The University of Tokyo   Master's Degree  

  • 2008.04
    -
    2012.03

    The University of Electro-Communications   Bachelor's Degree  

Research Areas

  • Inorganic/coordination chemistry / Inorganic compounds and inorganic materials chemistry

Research Interests

  • Inorganic Chemistry

  • Coordination Chemistry

  • Photochemistry

Awards

  • UBE学術振興財団 第65回学術奨励賞

    2025.04  

  • 東京大学 大学院工学系研究科 応用化学専攻 修了生総代

    2014.03  

  • 東京大学 大学院工学系研究科 応用化学専攻 優秀発表賞

    2014.03  

 

Papers

  • Structure and luminescence colour change of iridium(III) bis-terpyridine complex crystal triggered by water sorption/desorption

    Yusuke EndoMio KondoTomoe NakamuraShingo HattoriAkiko SekineSosuke, KojoKazuteru Shinozaki

    CrystEngComm    2026  [Refereed]  [International journal]

    DOI

  • Lamellar‐Cleavage‐Induced Triboluminescence in Discrete Chiral Complexes with Lanthanides

    Reo Ohno, Akira Saso, Yukina Yamamoto, Daisuke Hayauchi, Hitomi Ohmagari, Daisuke Saito, Shingo Hattori, Chika Nishimoto, Naofumi Nakayama, Ken Nakano, Suguru Ito, Shogo Kawaguchi, Masako Kato, Kazuyuki Ishii, Miki Hasegawa

    Chemistry – A European Journal   31 ( 68 ) e02824  2025  [Refereed]  [International journal]

    　View Summary

    Abstract

    Triboluminescence (TL), which is the light emission induced by mechanical stimuli, has attracted significant interest owing to its potential for energy conversion applications. Here, the TL mechanisms of chiral lanthanide complexes (LnL val , Ln = Eu, Tb, Sm, Dy, and Gd) were elucidated by focusing on the role of lamellar cleavage of the crystal structure. The modified drop tower system (DTS) quantifies mechanical stimuli used to observe the TL spectra. Chiral EuL val and TbL val exhibit intense TL, in contrast to the absence of TL in their racemic counterparts. Structural analyses revealed lamella‐like molecular stacking in the chiral crystals with anisotropic molecular orientations and flexibility along the c ‐axis. TL was reversibly observed by recrystallization when the crystal size was sufficiently large. Comparison of the TL and photoluminescence (PL) spectra, showed that TL of chiral LnL val was enhanced through photo‐antenna effects by the impact of lamellar cleavage. The TL values of the chiral Dy and Sm complexes were also evaluated. Furthermore, the absence of chemical reaction of the two nitrate ions with neighboring molecules in the lamella was confirmed. This system suggests the importance of the lamellar arrangement and provides potential design strategies for mechano‐responsive materials for TL activation of Ln complexes.

    DOI

  • Visualization of trap distribution in SrAl2O4:Eu2+,Dy3+ revealed by simulations of luminescence changes in charging and emission of persistent luminescence and thermoluminescence based on a random walk model

    Ryusuke Koizumi, Ryoya Takahashi, Shigeki Yamada, Shingo Hattori, Kazuteru Shinozaki

    Physical Chemistry Chemical Physics   27 ( 30 ) 15850 - 15857  2025  [Refereed]  [International journal]

    　View Summary

    A stochastic analysis using a random walk model can be used to visualize a potential energy diagram of electron traps involving persistent luminescence of SrAl2O4:Eu+,Dy3+.

    DOI

  • Front Cover: Recent Advances in Luminescence of Platinum Complexes in the Near Infrared Second Window

    Shingo Hattori, Kazuteru Shinozaki

    ChemPhotoChem   9 ( 6 ) e202580601  2025  [Refereed]  [International journal]

    DOI

  • Recent Advances in Luminescence of Platinum Complexes in the Near Infrared Second Window

    Shingo Hattori, Kazuteru Shinozaki

    ChemPhotoChem   9 ( 6 ) e202500041  2025  [Refereed]  [International journal]

    　View Summary

    The near infrared (NIR) optical window enables to observe biological tissue noninvasively through photoimaging using luminophores. Particularly, the light in the NIR II region of 1000–1400 nm between strong absorption bands of H2O and tissue chromophores is advantageous for photoimaging and phototherapies of deep tissue. Pt complexes possessing the high emission ability and the luminescence tunability are expected to be luminophores for deep imaging and photosensitizers of photodynamic therapy. Herein, the NIR II emission from Pt complexes designed by the strategy of the extension of ligand π conjugation and the aggregation by the Pt–Pt interaction from recent works is reviewed.

    DOI

  • Circularly Polarized Phosphorescence Properties of Binuclear Cyclometalated Platinum(II) Complexes Bearing Axially Chiral Schiff-Base Ligands

    Masahiro Ikeshita, Itsuki Shimizu, Shinya Watanabe, Tomoki Yamada, Seika Suzuki, Shota Tanaka, Shingo Hattori, Kazuteru Shinozaki, Yoshitane Imai, Takashi Tsuno

    Inorganic Chemistry   63 ( 50 ) 23642 - 23650  2024  [Refereed]  [International journal]

    DOI

  • Cover Feature: Sequential H/D Exchanges Resulting from Rollover‐Cyclometallation during Photoirradiation of Rhodium(III) Complex in Methanol‐d4

    Shota Tanaka, Shingo Hattori, Kazuteru Shinozaki

    Chemistry – A European Journal   30 ( 63 ) e202486303  2024  [Refereed]  [International journal]

    DOI

  • Sequential H/D Exchanges Resulting from Rollover‐Cyclometallation during Photoirradiation of Rhodium(III) Complex in Methanol‐d4

    Shota Tanaka, Shingo Hattori, Kazuteru Shinozaki

    Chemistry – A European Journal   30 ( 63 ) e202402067  2024  [Refereed]  [International journal]

    　View Summary

    Abstract

    We present the photoreaction of newly prepared bis(6,6’‐dimethyl‐2,2’‐bipyridine)(oxalato)rhodium(III) ([Rh(N N)2(ox)]+) in CD3OD. Photoirradiation of this complex causes the dissociation of ox, followed by the formation of the unprecedented Rh(III) complex with Rh−H and Rh−C σ bonds, [Rh(N N)(C N)(H)(CD3OD)]+ (C N=[6,6’‐dimethyl‐2,2’‐bipyridine]‐3‐yl‐κC3,κN1’). This hydride formation and cyclometallation spontaneously proceed owing to the conflict between the steric hindrance arising from the methyl groups of N N and the driving force for the structural change due to [Rh(N N)2]+ formation. Although [Rh(N N)(C N)(H)(CD3OD)]+ is initially converted to [Rh(N N)2]+ by photoirradiation, it is immediately regenerated by the rollover cyclometallation of the [Rh(N N)2]+ complex. [Rh(N N)(C N)(H)(CD3OD)]+ undergoes H/D exchange for the H atoms in the Rh−H bond and at the 3, 3’‐positions of the N N ligand during the photoirradiation. DFT calculations predict with reasonable certainty the spontaneous structural change of [Rh(N N)2]+ to [Rh(N N)(C N)(H)(CD3OD)]+ and the subsequent photodriven Rh−C bond rupture leading to the formation of [Rh(N N)2]+ accompanied by H/D exchange reactions.

    DOI

  • Photodynamic Effect of Amphiphilic N∧C∧N-Coordinated Platinum(II) Complexes in Human Umbilical Vein Endothelial Cells

    Shingo Hattori, Mizuki Ogishima, Tadaaki Nakajima, Shota Hosoya, Yuichi Kitagawa, Yasuchika Hasegawa, Shinji Nonose, Tomomi Sato, Kazuteru Shinozaki

    Inorganic Chemistry   63 ( 30 ) 13972 - 13979  2024  [Refereed]  [International journal]

    DOI

  • Circularly polarized phosphorescence with a large dissymmetry factor from a helical platinum(II) complex

    Masahiro Ikeshita, Shinya Watanabe, Seika Suzuki, Shota Tanaka, Shingo Hattori, Kazuteru Shinozaki, Yoshitane Imai, Takashi Tsuno

    Chemical Communications   60 ( 17 ) 2413 - 2416  2024  [Refereed]  [International journal]

    　View Summary

    A helical platinum(ii) complex exhibits intense red circularly polarized phosphorescence (CPP) with glum of 0.010 in the dilute solution state.

    DOI

  • Assembling of a Water‐Soluble N^C^N‐Coordinated Pt(II) Complex Aggregate Assisted by Carbon Dioxide in Basic Aqueous Solution

    Hiroyuki Mita, Shingo Hattori, Toshiyuki Sasaki, Satoshi Takamizawa, Kazuteru Shinozaki

    ChemSusChem   17 ( 2 ) e202301174  2024  [Refereed]  [International journal]

    　View Summary

    Abstract

    We report an unprecedented result of self‐aggregation of [Pt(L1)Cl] (HL1=1,3‐di(5‐carboxy‐2‐pyridyl)benzene) triggered by CO2 in basic aqueous solution. The color of basic aqueous solution containing [Pt(L1)Cl] changes from yellow to blue‐green during the aggregation resulted from a reaction with CO2 in air. Upon CO2 gas bubbling, strong and broad absorption bands of aggregate assigned to the metal‐metal‐to‐ligand charge‐transfer transition appeared at 701 and 1152 nm. Recrystallization of [Pt(L1)Cl] from Na2CO3 aqueous solution afforded polymorphic crystals of red and blue‐green forms. A single X‐ray crystallography revealed that the red form of crystal consists of a Pt−Pt stacked dimer bridged by CO32− ion and one of the carboxy groups of L1 is deprotonated. An elemental analysis provided evidence that the blue‐green crystal is constructed by linear array consisting of the [Pt(L2)(CO3)]3− (HL2=1,3‐di(5‐carboxylate‐2‐pyridyl)benzene) units. The formation process of blue‐green aggregate in aqueous solution was monitored through a transient absorption spectrum, and the absorption of aggregates involved in the spectral change were examined by a global analysis. A singular value decomposition and kinetic analysis provide that there are four species resulted from the self‐assembling reaction in the solution and the maximal degree of aggregation is at least 32‐mer.

    DOI

  • Kinetic Formation of Pt–Pt Dimers of Cationic and Neutral Platinum(II) Complexes under Rapid Freeze Conditions in Solution

    Shingo Hattori, Shusei Kawajiri, Akiko Sekine, Keisuke Sumi, Hitomi Narumiya, Kyouhei Sato, Kazuteru Shinozaki

    Inorganic Chemistry   62 ( 24 ) 9491 - 9500  2023  [Refereed]  [International journal]

    DOI

  • Luminescence color change of [3,4-difluoro-2,6-bis(5-methyl-2-pyridyl)phenyl-κ3N,C1,N′]cyanidoplatinum(II) by aggregation

    Shingo Hattori, Takumi Nakano, Nanako Kobayashi, Yuri Konno, Eiji Nishibori, Tomasz Galica, Kazuteru Shinozaki

    Dalton Transactions   51 ( 41 ) 15830 - 15841  2022  [Refereed]  [International journal]

    　View Summary

    A newly designed Pt(ii) complex showing a variety of emission colors depending on the degree of stacking is capable of sensing chloroform vapor.

    DOI

  • Vapochromism of iridium(III) bis-terpyridine complex based on modulation of halide-to-ligand charge transfer transition

    Shingo Hattori, Mio Kondo, Akiko Sekine, Kazuteru Shinozaki

    Dalton Transactions   51 ( 18 ) 7068 - 7075  2022  [Refereed]  [International journal]

    DOI

  • Reversible colour/luminescence colour changes of tetracyanoruthenium(II) complexes by sorption/desorption of water molecules in crystals

    Shingo Hattori, Tomoya Nagai, Akiko Sekine, Takuhiro Otsuka, Kazuteru Shinozaki

    Dalton Transactions   51 ( 4 ) 1474 - 1480  2022  [Refereed]  [International journal]

    DOI

  • Emission Intensity Enhancement for Iridium(III) Complex in Dimethyl Sulfoxide under Photoirradiation

    Shingo Hattori, Shuntaro Hirata, Kazuteru Shinozaki

    The Journal of Physical Chemistry B   125 ( 32 ) 9260 - 9267  2021  [Refereed]  [International journal]

    DOI

  • Vortex-Induced Harmonic Light Scattering of Porphyrin J-Aggregates

    Shingo Hattori, Michèle Moris, Kazuteru Shinozaki, Kazuyuki Ishii, Thierry Verbiest

    The Journal of Physical Chemistry B   125 ( 10 ) 2690 - 2695  2021  [Refereed]  [International journal]  [International coauthorship]

    DOI

  • Dual emission from an iridium(III) complex/counter anion ion pair

    Wataru Ito, Shingo Hattori, Mio Kondo, Hiroki Sakagami, Osamu Kobayashi, Takayoshi Ishimoto, Kazuteru Shinozaki

    Dalton Transactions   50 ( 5 ) 1887 - 1894  2021  [Refereed]  [International journal]

    　View Summary

    <p>[Ir(tpy)2](PF6)3 (tpy = 2,2’:6’,2’’-terpyridine) dissolved in CH3CN was found to exhibit dual color luminescent emission depending on the excitation wavelength. Specifically, blue and green emissions were obtained with excitation at...</p>

    DOI

  • H/D solvent isotope effects on the photoracemization reaction of enantiomeric the tris(2,2′-bipyridine)ruthenium(ii) complex and its analogues

    Masahiro Asahara, Haruhiko Kurimoto, Masato Nakamizu, Shingo Hattori, Kazuteru Shinozaki

    Physical Chemistry Chemical Physics   22 ( 11 ) 6361 - 6369  2020  [Refereed]  [International journal]

    　View Summary

    <p>This work assessed solvent isotope effects on the photoracemization rate and emission lifetime for [Ru(bpy)3]2+ (bpy = 2,2′-bipyridine) in water.</p>

    DOI

  • Recent advances in studies on the magneto-chiral dichroism of organic compounds

    Kazuyuki Ishii, Shingo Hattori, Yuichi Kitagawa

    Photochemical & Photobiological Sciences   19 ( 1 ) 8 - 19  2020  [Refereed]  [International journal]

    　View Summary

    <p>Magneto-chiral dichroism is described in terms of devices and synthesis, and is a clue to explain the homochirality of life.</p>

    DOI

  • Chiral Supramolecular Nanoarchitectures from Macroscopic Mechanical Rotations: Effects on Enantioselective Aggregation Behavior of Phthalocyanines

    Mizuki Kuroha, Shohei Nambu, Shingo Hattori, Yuichi Kitagawa, Kazuhiro Niimura, Yuki Mizuno, Fujihiro Hamba, Kazuyuki Ishii

    Angewandte Chemie   131 ( 51 ) 18625 - 18630  2019  [Refereed]  [International journal]

    　View Summary

    Abstract

    Fluid dynamics, resulting from the macroscopic mechanical rotation of either a rotary evaporator or a magnetic stirrer, has been shown to selectively induce one of two enantiomers (mirror‐image structures) in certain nanoscale supramolecules. As an alternative to giving a chiral twist to synthesized supramolecules or polymers, it is a challenge to reproducibly prepare chiral species by only using macroscopic mechanical rotations. Demonstrated here is a highly reproducible method for rotary‐evaporation‐induced enantioselective H‐aggregation of achiral phthalocyanines. Chiral induction mechanisms are proposed by using the chiroptical‐sign‐based absolute structures. These results will provide insight to the origin of the homochirality of life, and serves as a pioneering study in a novel scientific field in terms of admixing nanoscale molecular chemistry and macroscopic fluid dynamics.

    DOI

  • Chiral Supramolecular Nanoarchitectures from Macroscopic Mechanical Rotations: Effects on Enantioselective Aggregation Behavior of Phthalocyanines

    Mizuki Kuroha, Shohei Nambu, Shingo Hattori, Yuichi Kitagawa, Kazuhiro Niimura, Yuki Mizuno, Fujihiro Hamba, Kazuyuki Ishii

    Angewandte Chemie International Edition   58 ( 51 ) 18454 - 18459  2019  [Refereed]  [International journal]

    　View Summary

    Abstract

    Fluid dynamics, resulting from the macroscopic mechanical rotation of either a rotary evaporator or a magnetic stirrer, has been shown to selectively induce one of two enantiomers (mirror‐image structures) in certain nanoscale supramolecules. As an alternative to giving a chiral twist to synthesized supramolecules or polymers, it is a challenge to reproducibly prepare chiral species by only using macroscopic mechanical rotations. Demonstrated here is a highly reproducible method for rotary‐evaporation‐induced enantioselective H‐aggregation of achiral phthalocyanines. Chiral induction mechanisms are proposed by using the chiroptical‐sign‐based absolute structures. These results will provide insight to the origin of the homochirality of life, and serves as a pioneering study in a novel scientific field in terms of admixing nanoscale molecular chemistry and macroscopic fluid dynamics.

    DOI

  • Molecular Power Spring: Circular Dichroism Inversion of Polythiophene Aggregates from the Right-Handed Helix to Left-Handed Helix

    Shingo Hattori, Stefaan Vandendriessche, Toshiyuki Hirano, Fumitoshi Sato, Guy Koeckelberghs, Thierry Verbiest, Kazuyuki Ishii

    The Journal of Physical Chemistry B   123 ( 13 ) 2925 - 2929  2019  [Refereed]  [International journal]  [International coauthorship]

    DOI

  • Encapsulation of zinc phthalocyanine into bovine serum albumin aggregates

    Takanori Yokoi, Shingo Hattori, Kazuyuki Ishii

    Journal of Coordination Chemistry   72 ( 4 ) 707 - 715  2019  [Refereed]  [International journal]

    DOI

  • Whole-cell circular dichroism difference spectroscopy reveals an in vivo-specific deca-heme conformation in bacterial surface cytochromes

    Yoshihide Tokunou, Punthira Chinotaikul, Shingo Hattori, Thomas A. Clarke, Liang Shi, Kazuhito Hashimoto, Kazuyuki Ishii, Akihiro Okamoto

    Chemical Communications   54 ( 99 ) 13933 - 13936  2018  [Refereed]  [International journal]  [International coauthorship]

    DOI

  • Spiral Eu(III) coordination polymers with circularly polarized luminescence

    Yasuchika Hasegawa, Yui Miura, Yuichi Kitagawa, Satoshi Wada, Takayuki Nakanishi, Koji Fushimi, Tomohiro Seki, Hajime Ito, Takeshi Iwasa, Tetsuya Taketsugu, Masayuki Gon, Kazuo Tanaka, Yoshiki Chujo, Shingo Hattori, Masanobu Karasawa, Kazuyuki Ishii

    Chemical Communications   54 ( 76 ) 10695 - 10697  2018  [Refereed]  [International journal]

    DOI

  • Evaporation rate-based selection of supramolecular chirality

    Shingo Hattori, Stefaan Vandendriessche, Guy Koeckelberghs, Thierry Verbiest, Kazuyuki Ishii

    Chemical Communications   53 ( 21 ) 3066 - 3069  2017  [Refereed]  [International journal]  [International coauthorship]

    DOI

  • Magneto-chiral dichroism measurements using a pulsed electromagnet

    Shingo Hattori, Yusuke Yamamoto, Tomohiro Miyatake, Kazuyuki Ishii

    Chemical Physics Letters   674   38 - 41  2017  [Refereed]  [International journal]

    DOI

  • Determination of the Absolute Configuration of Side Chains of Basic Amino Acid Residues Using the Water-Soluble Porphyrin-Based Exciton Chirality Method

    Shingo Hattori, Kengo Akagawa, Kazuaki Kudo, Kazuyuki Ishii

    The Journal of Physical Chemistry B   120 ( 39 ) 10280 - 10287  2016  [Refereed]  [International journal]

    DOI

  • Magneto-chiral dichroism of aromatic π-conjugated systems

    Shingo Hattori, Kazuyuki Ishii

    Optical Materials Express   4 ( 11 ) 2423 - 2423  2014  [Refereed]  [International journal]

    DOI

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Research Projects