MOMMA, Toshiyuki

写真a

Affiliation

Faculty of Science and Engineering, School of Advanced Science and Engineering

Job title

Professor

Homepage URL

http://www.f.waseda.jp/momma/

Concurrent Post 【 display / non-display

  • Faculty of Science and Engineering   Graduate School of Advanced Science and Engineering

Research Institute 【 display / non-display

  • 2020
    -
    2022

    理工学術院総合研究所   兼任研究員

Degree 【 display / non-display

  • 早稲田大学   博士(工学)

  • Waseda University   Dr. of Engineering

Professional Memberships 【 display / non-display

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    表面技術協会

  •  
     
     

    高分子学会

  •  
     
     

    日本化学会

  •  
     
     

    The Electrochemical Soc.(米国電気化学会)

  •  
     
     

    電気化学会

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Research Areas 【 display / non-display

  • Electron device and electronic equipment

Research Interests 【 display / non-display

  • Applied Physical Chemistry,Composite Materials,Electrochemical Energy Devices

Papers 【 display / non-display

  • Immobilization of Target-Bound Aptamer on Field Effect Transistor Biosensor to Improve Sensitivity for Detection of Uncharged Cortisol

    Hiroki HAYASHI, Ryo TOYAMA, Ryota TAKIBUCHI, Sho HIDESHIMA, Shigeki KUROIWA, Naoto KANEKO, Katsunori HORII, Keishi OHASHI, Toshiyuki MOMMA, Tetsuya OSAKA

    Electrochemistry   89 ( 2 ) 134 - 137  2021.03

    DOI

  • High-rate and high sulfur-loaded lithium-sulfur batteries with a polypyrrole-coated sulfur cathode on a 3D aluminum foam current collector

    Natsuki Nakamura, Tokihiko Yokoshima, Hiroki Nara, Hitoshi Mikuriya, Ayahito Shiosaki, Seongki Ahn, Toshiyuki Momma, Tetsuya Osaka

    Materials Letters   285   129115 - 129115  2021.02

    DOI

  • Effect of fluoroethylene carbonate and vinylene carbonate additives on full-cell optimization of Li-ion capacitors

    Seongki Ahn, Minori Fukushima, Hiroki Nara, Toshiyuki Momma, Wataru Sugimoto, Tetsuya Osaka

    ELECTROCHEMISTRY COMMUNICATIONS   122  2021.01

     View Summary

    Lithium-ion capacitors (LICs) operate by two mechanisms, namely a double-layer mechanism based on a capacitor-like positive electrode and the intercalation mechanism of a battery-like negative electrode. Hence, well-designed reaction kinetics between the positive electrode and negative electrode are essential for optimizing LIC full-cell configurations. In this study, we investigated the influences of fluoroethylene carbonate (FEC) or vinylene carbonate (VC) as electrolyte additives on full-cell performance of LICs. We confirmed that the internal resistance of graphite increased with the use of FEC, which degraded the cyclability of the LIC full-cell. Conversely, LICs consisting of the VC additive had good cyclability over 4000 cycles owing to the solid electrolyte interphase (SEI) containing polymeric species. This detailed investigation into the function of SEI compounds derived from VC additives and their effect on cyclability will provide new insights into optimization of LIC full-cell configurations with appropriate electrolyte additives.

    DOI

  • Effect of Mass Balancing on Cell Performance and Electrochemical Investigation of Sn–Ni Alloy as Anode for Li-Ion Capacitors

    Seongki Ahn, Yusuke Nakamura, Hiroki Nara, Toshiyuki Momma, Wataru Sugimoto, Tetsuya Osaka

    Journal of The Electrochemical Society   167 ( 13 ) 130512 - 130512  2020.09

    DOI

  • Tetrameric jacalin as a receptor for field effect transistor biosensor to detect secretory IgA in human sweat

    Hiroki Hayashi, Naoki Sakamoto, Sho Hideshima, Yoshitaka Harada, Mika Tsuna, Shigeki Kuroiwa, Keishi Ohashi, Toshiyuki Momma, Tetsuya Osaka

    Journal of Electroanalytical Chemistry   873   114371 - 114371  2020.09

    DOI

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Books and Other Publications 【 display / non-display

  • Chapter. 5. Advanced negative electrodes of Nano-scale for Li ion batteries in "Nanoscale Technology for Advanced Lithium Batteries" Ed. T. Osaka and Z. Ogumi

    Toshiyuki Momma, Tetsuya Osaka

    Springer Science+Business Media  2013.11 ISBN: 9781461486749

  • 第6版電気化学便覧 編集 および 5.8.3周波数応答と電気的等価回路 および 5.9.8イメージング 著

    門間聰之

    丸善出版  2013.01 ISBN: 9784621084137

  • 実力がつく電気化学 —基礎と応用—

    逢坂哲彌, 直井勝彦, 門間聰之

    朝倉書店  2012.03 ISBN: 9784254140934

  • 電池ハンドブック 11編 1章 概要 2章 電気二重層キャパシター

    章 逢坂哲彌, 門間聰之, 奈良洋希, 章 門間聰之

    株式会社オ ー ム 社  2010.02 ISBN: 9784274208058

  • CONDUCTIVE POLYMERS: Electroplating of Organic Films in Modern Electroplating 5th Ed. Edited by Mordechay Schlesinger and Milan Paunovic

    T. Osaka, S. Komaba, T. Momma

    John Wiley &Sons, Inc.  2010 ISBN: 9780470167786

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Misc 【 display / non-display

  • Electrochemical Impedance Analysis for Discharging Process of Sulfur Cathode in Polysulfide Soluble DOL/DME-based Electrolyte

    橋都宏汰, 門間聰之, 横島時彦, 戸ヶ崎徳大, 中尾愛子, 奈良洋希, 逢坂哲彌, 家路豊成

    電気化学会大会講演要旨集(CD-ROM)   87th  2020

    J-GLOBAL

  • Electrochemical Impedance Analysis for Discharging process of Sulfur Cathode in Ionic Liquid Electrolyte

    平柳朋恵, 橋都宏汰, 門間聰之, 横島時彦, 戸ヶ崎徳大, 中尾愛子, 奈良洋希, 逢坂哲彌, 家路豊成

    電気化学会大会講演要旨集(CD-ROM)   87th  2020

    J-GLOBAL

  • プレドープ時VC添加によるSn-Ni合金負極を用いたリチウムイオンキャパシタのサイクル特性向上

    中村優友, 門間聰之, 門間聰之, 杉本渉, 奈良洋希, 逢坂哲彌

    電気化学会大会講演要旨集(CD-ROM)   86th  2019

    J-GLOBAL

  • FABRICATION OF APTAMER-IMMOBILIZED FET BIOSENSOR FOR SENSITIVE DETECTION OF UNCHARGED MOLECULES USING TARGET-APTAMER COMPLEX

    遠山良, 黒岩繁樹, 林宏樹, 大橋啓之, 門間聰之, 逢坂哲彌

    Chemical Sensors   35 ( Supplement B )  2019

    J-GLOBAL

  • Fabrication Process of Li2S Cathode for Li-S Battery by Chemical Lithiation with Li Naphthalenide

    春山真也, 横島時彦, 門間聰之, 門間聰之, 奈良洋希, 逢坂哲彌

    電池討論会PDF要旨集(CD-ROM)   60th  2019

    J-GLOBAL

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Industrial Property Rights 【 display / non-display

  • 正極材および蓄電デバイス

    門間 聰之

    Patent

  • レクチン固定化半導体センシングデバイス及び糖化合物の検出方法

    逢坂 哲彌, 秀島 翔, 門間 聰之, 林 宏樹

    Patent

  • リチウム硫黄二次電池

    逢坂 哲彌, 門間 聰之, 中村 夏希, 三栗谷 仁

    Patent

  • 電気化学システム、および、電気化学システムの作動方法

    逢坂 哲彌, 門間 聰之, 横島 時彦, 向山 大吉, 奈良 洋希

    Patent

  • リチウム硫黄電池の製造方法、および、リチウム硫黄電池

    門間 聰之, 逢坂 哲彌, 横島 時彦, 奈良 洋希

    Patent

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Awards 【 display / non-display

  • Electrochemistry Communications 2007 Best Cited paper Award

    2007  

  • Electrochemical Society of Japan Award for Young Electrochemists

    2001.04  

Research Projects 【 display / non-display

  • Creating Soft-Batteries by Simple and Rapid Processes and Innovating Capacity by Reversible Structure Change

    Project Year :

    2016.05
    -
    2021.03
     

  • Creation of three-dimensional nano-scale interface at large scale and its application to electric energy storage devices

    Project Year :

    2013.10
    -
    2017.03
     

     View Summary

    Toward innovation of electric energy storage using emerging capacitive materials, three-dimensional nanostructured electrodes are developed via simple, rapid, high-yield processes. Si has a ten-times higher theoretical anode capacity than graphite. Several μm-thick, porous Si and Si-Cu alloy anodes are formed directly on Cu current collectors in 1 min from inexpensive and safe sources of their bulks via rapid vapor deposition method. Over 99.6 wt%-pure, submillimeter-long few-wall carbon nanotubes (CNTs) are produced semi-continuously via fluidized-bed method, which are ready for use without purification. CNTs are co-dispersed and co-filtrated with capacitive materials such as activated carbon, lithium cobalt oxide, and graphite to create self-supporting, tens μm-thick films. Such films work as electrodes with line contact with metal wires, and such architecture will minimize the use of heavy current collectors of metals in electrochemical capacitors and rechargeable batteries

  • Establishment of Electrochemical Device Engineering

    Project Year :

    2008.06
    -
    2013.03
     

     View Summary

    Based on the researches for development of functional materials with the control of solid-liquid interface and for development of devices with the practical use of nano- and meso-structures and phenomena at the interface, the establishment of Electrochemical Device Engineering was promoted. To establish Electrochemical Device Engineering on the basis of Electrochemical Nanotechnology, the practical devices utilizing the outcome of research and the dimensions for appearance of function and design of solid-liquid interface were set as the warp and weft of this academic discipline

  • Study of recording and reproducing process in high density magnetic recording

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    1. Analytical method for solving magnetic field distribution of magnetic heads : Integral Equation / Fourier Analysis Method have been constructed for solving magnetic head field distributions2. Analytical method for solving recording and reproducing characteristics : Recording and reproducing characteristics on single layer perpendicular recording media and double-layered perpendicular recording media have been analyzed.3. Theoretical analysis of noise from magnetic recording media : Power spectral density of noise caused from the magnetic clusters in the recording layer has been analyzed theoretically. The cluster size calculated based on the theory agreed well with that obtained experimentally by a magnetic force microscope.4. Design of magnetic materials for recording media :It has been found that a new composite recording medium having a Co/Pd artificial lattice magnetic layer on an amorphous carbon underlayer has extremely large magnetic anisotropy field (≒20kOe), high recording resolution and low noise properties

  • Creation of Novel Ion Conducting Membrane by Nano-Micro Structural Control

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    Novel proton conducting membranes composed of proton conducting polymers and porous matrices were prepared for direct methanol fuel cells (DMFCs). As the matrix for the composite membrane, a three-dimensionally ordered macroporous (3DOM) membrane with adequate mechanical strength was successfully obtained by use of silica or polyimide. Due to mechanical suppression of polymer expansion by the matrix, the composite membrane exhibited high dimensional stability. As a result, the methanol permeability less than a few tenths of that of Nafion【○!R】 membrane and high cell performance by feeding a desired high-concentrated methanol solution (10 mol dm-3) were successfully achieved for the first time ever. The components of the composite membrane were inexpensive, so that the production cost could be also decreased less than a few tenths of that of Nafion【○!R】 membrane. The filling state of the polymer electrolyte in the composite membrane was revealed by transmission electron microscope observation, which was conducted as a joint study with Group D01. Therefore, the relationship between the nano-structure of the composite membrane and the resulting properties became clear and the membrane properties could be improved. As another type of the electrolyte membrane, the 3DOM silica matrix filled with a novel room-temperature molten salt that was synthesized by Group C01, was evaluated. The obtained composite membrane worked stably over 100 h under dry and high-temperature condition, suggesting the realization of high temperature DMFC for electric vehicles.Researches for improving cell performance were also conducted. It was appeared that the quality between the membrane and a catalyst layer greatly influenced the cell performance by A.C. impedance measurement. As one of solutions, we performed a surface modification of the 3DOM silica by sulfonic acid groups, and the cell performance was successfully enhanced. Application of electrophoretic deposition (EPD) process to fabricate a catalyst layer onto the membrane was also studied as another method. The obtained catalyst layer by the EPD process was uniform and porous compared to that prepared by an ordinary method, i.e. a decal transfer process. This structure was favorable to gas diffusion, resulting in improvement of Pt utilization up to 76%. Accordingly, the MEA prepared by the EPD process exhibited higher cell performance with half amount of Pt loadings compared to the ordinary one. The latter process has been introduced all over the world by Electrochemical Society as Technical highlight and has attracted much attention

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Presentations 【 display / non-display

  • 交流インピーダンス法によるVC 添加下での微小参照極入りラミネート型リチウムイオン電池初期劣化解析

    第54回電池討論会 

    Presentation date: 2013.10

  • 微細参照極入りラミネート型リチウムイオン電池の電極表面へのVC 添加による影響

    第54回電池討論会 

    Presentation date: 2013.10

  • 矩形波インピーダンス法を用いたリチウムイオン二次電池の状態評価における入力波形の影響

    第54回電池討論会 

    Presentation date: 2013.10

  • 矩形波インピーダンス法を用いた市販リチウムイオン電池の状態解析

    第54回電池討論会 

    Presentation date: 2013.10

  • Cu embedded Si-O-C composite anode synthesized by electrochemical method for thick deposition of active material

    Presentation date: 2013.10

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Specific Research 【 display / non-display

  • リチウム空気電池実現のための負極/電解質系探索

    2014  

     View Summary

    Li空気電池において大気中から侵入するH2O、CO2、N2、Ar等の影響を検討した。電解液中のH2O量が少ない場合のクーロン効率は55 %を示す一方、CO2およびH2Oが共存した場合、クーロン効率は最大約90 %に達した。Li空気電池の電解液として広く研究されているDMSOはLi負極のクーロン効率が低いとされているが、SEI表面および内部を無機層で構成することでクーロン効率が85 %以上になることも見出した。

 

Syllabus 【 display / non-display

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